Protein Powder Rheology

Protein PowdersProtein Powders – Differences in handling dairy vs. vegan protein powder

Soy, pea and hemp protein powder shakes have become popular plant-based sources for vegetarians and vegans, as an alternative to whey-based protein shakes. Despite the protein content of these powders being similar, their handling properties are quite different. Quality control processes for incoming powder typically only focus on the chemical composition. This can result in a whole host of processing nightmares downstream, as one tries to move a powder from storage and through the various stages of a production or filling line.

There are multiple contributing factors that can affect how a powder evacuates a vessel. The flow function, bulk density, compressibility/compactability of the powder, and its interaction with the surface of its container are all key considerations. These small differences can scale up drastically, as we’ll see from our comparison of protein powders below.

From a process control perspective, getting a heads up on powder handling characteristics can help avoid the dreaded hammer rash seen on hoppers, or your silo accidentally imploding on you…

Contact us now for a quick and easy characterisation of the handling behaviour of your powders.

Powder Handling – Arching, ratholing and avalanching

Mass flow the first powder in is the first powder out, in core flow the first powder in is the last powder out. For perishable powders it is generally preferable to achieve a “mass flow” condition, whereby the first powder into the silo is the first powder to evacuate. It may not be possible to achieve this condition due to available headroom, prohibitive costs or simply because the process can’t be changed at this point. It may also not provide additional benefits where small-batch processes ensure that the powder is cleared from the system in a reasonable time frame to negate perishability issues.

“Core flow” or “funnel flow” may be adequate but can be susceptible to potential flow issues. These may be predicted and potentially avoided with a good understanding of powder handling characteristics.

Powder Flow

Arching or bridging is a flow-arresting situation whereby the powder mass creates a structure (such as a dome or a bridge) above the outlet hole inhibiting flow completely. Ratholing, another flow arresting situation, is when material directly above the outlet flows but the rest of the powder mass closest to the walls does not, creating a tunnel. The collapse and uncontrolled overflowing of powder can also be an issue and is sometimes referred to as avalanching.

The half-angle of hopper walls and diameter of the outlet are two physical dimensions that are normally considered when designing a powder handling system to avoid these issues. The minimum requirements for these values can be determined using the following equation.

Hopper half angle equation

Whereby “B” is the minimum diameter for a hopper outlet, Fc is the critical unconfined yield stress of the powder, H(θ) is a function of the geometry of the outlet, ρb is the bulk density of the powder and g is gravity. The values required to resolve this equation can be derived experimentally using the methods below.

Powder Flow Function – Flowability of Protein Powder

A powder flow function is a measure of a powder’s failure strength (known as its unconfined failure strength) as a function of applied stresses (major principle consolidation stresses). To obtain the flow function a shear cell powder flow tester is employed, where the yield strength of a powder mass is measured as a function of a range of normal stresses following a defined “pre-consolidation” conditioning step. This attempts to simulate the stresses experienced by a powder mass in a hopper or silo.

Unconfined failure strength of protein powders plotted as a function of major principal consolidating stress. In general terms, the more shallow the gradient of the curve, the more free flowing the powder. In this example we can see that under low consolidation stresses, soy, hemp and whey handle pretty similarly. However as you gradually increase the consolidation stress, we start to see a greater degree of differentiation; whey becomes less flowable, needing greater shear stresses to get flowing than either soy or hemp at higher consolidating stresses. Pea protein powder is a standout in this test and does not flow as well as any of the other protein powders, even at low consolidation stresses.

Bulk Density – Compressibility of Protein Powder

Bulk density is often taken to be a constant for many powder flow calculations. However, if your powder is full of irregular shaped or sized, elastic or brittle particles, this value can change significantly depending on the stresses applied to it. A bulk density test seeks to quantify the “compressibility” of powders as a function of consolidating stresses. If the line is flat across a range of normal stresses, the powder is incompressible, if the density rises, then the powder is compressible.

From a process perspective, dense powders provide a higher downwards force in an equivalent volume column of powder than a less dense one. This is important for understanding delivery of a known amount of material over time; a highly compressible powder may manifest problems with variable mass or volume delivery as fill levels and therefore normal stresses in the hopper change.

Bulk density of protein powders plotted as a function of Normal stress In our comparison of protein powders hemp protein has the highest bulk density followed then by pea protein, soya protein and finally whey protein having the lowest bulk density. All powders show some level of compressibility / compactability over the range of normal stresses we investigated.

Wall Friction Angle of Protein Powder

So far we have looked at physical properties that focus on behaviours of the powder interacting with itself; the main properties being internal friction, cohesive forces and compactiability. The interaction a powder has with its container walls, either in a silo or upon hopper surfaces, can also have a highly influential impact on its ease of delivery.

A wall friction test is similar in design to a flow function test but instead measures the frictional force as the powder mass slides against a chosen surface whilst exposed to a range of load or normal stresses. The ratio of sliding force to load force is quite simply the coefficient of friction for the powder-surface system however, in the powder testing and hopper design world, “wall friction angles” are the preferred reporting norm. Wall friction angle is merely the inverse tangent of the coefficient of friction. Wall friction angle can also be thought of as the angle to which a surface must be reduced to cease the sliding of a powder mass atop it.

Wall friction angle of protein powders plotted as a function of Normal stress From our results it appears that pea protein powder generates the highest friction with our test surface (in this case a 304 stainless steel with a 2B finish) under low normal stresses. However, as normal stress increases, the angle required to cause the powder to slide off decreases. Generally, in order of least steep to most steep, whey protein slides on our test surface most easily, followed by soya then hemp protein.

If you are interested in exploring this topic in more detail, or have questions about how we can perform this testing for you, please feel welcome to contact us now.